Training Thermodynamics Math Heat Engines and Carnot Efficiency
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Heat Engines and Carnot Efficiency

24 min Thermodynamics Math

Heat engines convert thermal energy into mechanical work, and the Carnot cycle defines the theoretical maximum efficiency any engine can achieve between two temperature reservoirs. The Carnot efficiency η = 1 − TC/TH depends only on the absolute temperatures of the hot and cold reservoirs. Real engines — gasoline, diesel, jet turbines — always fall short of this ideal, but understanding the Carnot limit lets you evaluate and compare engine designs quantitatively.

Heat Engines and Carnot Efficiency

Every engine that converts heat to work is constrained by a simple ratio — the Carnot efficiency.

First Law of Thermodynamics

$$\Delta U = Q - W$$

Change in internal energy = heat added minus work done by the system.

Thermal Efficiency

$$\eta = \frac{W_{\text{out}}}{Q_{\text{in}}} = 1 - \frac{Q_{\text{out}}}{Q_{\text{in}}}$$

Carnot Efficiency (Maximum possible)

$$\eta_{\text{Carnot}} = 1 - \frac{T_C}{T_H}$$

Temperatures in Kelvin. No real engine can exceed this.

Example 1

A power plant: $T_H = 800$ K, $T_C = 300$ K. Max efficiency?

  1. $\eta = 1 - 300/800 = 1 - 0.375 = 62.5\%$.
Example 2

An engine absorbs 1000 J and exhausts 600 J. Find efficiency and work output.

  1. $W = Q_{in} - Q_{out} = 400$ J.
  2. $\eta = 400/1000 = 40\%$.
Example 3

What $T_H$ is needed for 70% Carnot efficiency if $T_C = 300$ K?

  1. $0.70 = 1 - 300/T_H$ → $T_H = 300/0.30 = 1000$ K = 727°C.

Practice Problems

1. Carnot efficiency: $T_H = 500$ K, $T_C = 300$ K.
2. Engine absorbs 2000 J, outputs 500 J work. Efficiency?
3. How much heat is exhausted in Problem 2?
4. Can any engine have 100% efficiency? Why?
5. Find $T_C$ if $T_H = 600$ K and Carnot efficiency is 50%.
6. A Carnot engine has $\eta = 0.4$ and absorbs 5000 J. Work done?
Show Answer Key

1. $1 - 300/500 = 40\%$

2. $500/2000 = 25\%$

3. $2000 - 500 = 1500$ J

4. No — would require $T_C = 0$ K, which is unreachable.

5. $T_C = T_H(1-\eta) = 600(0.5) = 300$ K

6. $W = 0.4 \times 5000 = 2000$ J

Carnot Efficiency Calculator
Carnot efficiency η
Work output W
Heat rejected Qᴄ
COP (if reversed / refrigerator)